Di-μ-chlorido-bis­{[2-(2-pyridylmethyl­amino)ethanesulfonato-κ3 N,N′,O]copper(II)}

نویسندگان

  • Zhong-Xiang Du
  • Jian-Hua Qin
  • Jian-Ge Wang
چکیده

In the title compound, [Cu(2)(C(8)H(11)N(2)O(3)S)(2)Cl(2)], the Cu atoms are five-coordinated in a distorted square-pyramidal geometry by three donor atoms of the deprotonated anionic 2-(2-pyridylmethyl-amino)ethanesulfonate (pmt) ligand and two Cl atoms. The Cl atoms bridge two Cu atoms, giving a binuclear structure; the centroid of the Cu(2)Cl(2) ring lies on a crystallographic center of inversion. The complex is stabilized by hydrogen bonds and π-π stacking inter-actions [average inter-planar distance = 3.4969 (1) Å and ring-centroid separation distance = 4.1068 (4) Å].

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Di-μ-chlorido-bis­{[2-(8-quinol­yloxy)­acetato-κ3 N,O 1,O 2]copper(II)}

The title compound, [Cu(2)(C(11)H(8)NO(3))(2)Cl(2)], is a bicopper(II) complex. Each Cu(II) ion is five-coordinated by two O atoms and one N atom from the (8-quinol-yloxy)acetate ligand, and by two μ(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl(2)NO(2) coordination environment. Each (8-quinol-yloxy)acetate anion acts as a tridentate chelating ligand. In the crystal str...

متن کامل

Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}

The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is penta-coordinated by three chloride ligands, a pyridine N-oxide O atom and a water mol-ecule. Intra- and inter-molecular O-H⋯O hydrogen bonds occur between the coordinated water mol-ecules and the uncoordinated and c...

متن کامل

Di-μ-chlorido-bis­[chlorido(1,4,6-trimethyl-6-nitro-1,4-diazepine)copper(II)]

The title neutral copper complex, [Cu(2)Cl(4)(C(8)H(17)N(3)O(2))(2)], shows a binuclear center with a Cu-(μ-Cl)(2)-Cu core, in which each copper ion is coordinated by the N,N,O donor atoms of the tridentate ligand 1,4,6-trimethyl-6-nitro-1,4-diazepine (meaaz-NO(2)) and three chloride exogenous ligands. Each metal ion is facially coordinated by meaaz-NO(2) through N,N,O donor atoms, whereas two ...

متن کامل

Bis(μ-l-arginine-κ3 N 2,O:O′)bis­(l-arginine-κ2 N 2,O)tetra-μ-chlorido-tetra­chlorido­tetra­copper(II)

The title compound, [Cu4Cl8(C6H14N4O2)4], contains four mol-ecules in the asymmetric unit. In the mol-ecular structure, each of the four Cu(2+) ions binds to three Cl atoms, one N atom and one O atom, resulting in distorted square-pyramidal coordination environments. The molecular structure is stabilized by weak C-H⋯O and N-H⋯Cl hydrogen bonds. The crystal structure exhibit weak inter-molecular...

متن کامل

Di-μ-acetato-κ4 O:O-bis­({2-[(piperidin-2-ylmeth­yl)imino­meth­yl]phenolato-κ3 N,N′,O}copper(II)) monohydrate

In the binuclear centrosymmetric title compound, [Cu(2)(C(13)H(17)N(2)O)(2)(C(2)H(3)O(2))(2)]·H(2)O, the Cu(II) atom is coordin-ated by two N atoms and one O atom from the Schiff base ligand and an acetate O atom in a distorted suare-planar geometry. The water O atom is invoved in three different hydrogen-bonding interactions, as donor to the acetate O atom and to the the ligand O atom and as a...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008